Solution
- Solution: A homogeneous mixture of two or more substances (solute and solvent) where the solute is uniformly distributed throughout the solvent.
Types of Solutions:
Solid Solutions: Solute is a solid, solvent is a solid (e.g., alloys).
- Liquid Solutions: Solute is a liquid, solvent is a liquid (e.g., alcohol in water).
- Gaseous Solutions: Solute is a gas, solvent is a gas (e.g., air).
Concentration of Solutions:
- Concentration: The amount of solute dissolved in a given amount of solution.
Units of Concentration:
- Volume percentage (% v/v): Milliliters of solute per 100 milliliters of solution.
- Molarity (M): Moles of solute per liter of solution.
- Molality (m): Moles of solute per kilogram of solvent.
- Interconversion of Concentration Units: Calculations exist to convert between different units based on solution density and solute molar mass.
3. Colligative Properties:
- Colligative properties: Properties of a solution that depend only on the concentration of solute particles, not their identity.
- Examples:
- Vapor pressure lowering: Solute presence lowers the solvent's vapor pressure compared to the pure solvent.
- Boiling point elevation: The boiling point of a solution is higher than that of the pure solvent.
- Freezing point depression: The freezing point of a solution is lower than that of the pure solvent.
- Osmotic pressure: The pressure required to prevent the flow of solvent across a semipermeable membrane separating a solution from pure solvent.
4. Solubility:
- Solubility: The maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure.
- Factors affecting solubility:
- Nature of solute and solvent: Similar structures tend to be more soluble in each other.
- Temperature: Generally, solubility increases with temperature.
- Pressure: For gaseous solutes, solubility increases with pressure.
5. Ideal and Non-ideal Solutions:
- Ideal solution: A hypothetical solution that exhibits perfect colligative property behavior based solely on solute concentration.
- Non-ideal solution: Real-world solutions that deviate from ideal behavior due to interactions between solute and solvent particles. These deviations can be positive or negative.
6. Applications of Solutions:
- Solutions are fundamental in various fields, including:
- Chemistry: Separations, purification, reactions.
- Biology: Physiological fluids, transport processes.
- Pharmacy: Drug delivery, formulations.
- Environmental science: Pollution control, remediation.
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