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Friday, March 8, 2024

Solution : Class 12

Friday, March 08, 2024

 Solution

  • Solution: A homogeneous mixture of two or more substances (solute and solvent) where the solute is uniformly distributed throughout the solvent.

Types of Solutions:
Solid Solutions: Solute is a solid, solvent is a solid (e.g., alloys).
    • Liquid Solutions: Solute is a liquid, solvent is a liquid (e.g., alcohol in water).
    • Gaseous Solutions: Solute is a gas, solvent is a gas (e.g., air).

Concentration of Solutions:

  • Concentration: The amount of solute dissolved in a given amount of solution.

Units of Concentration:
    Mass percentage (% m/m): Grams of solute per 100 grams of solution.
      • Volume percentage (% v/v): Milliliters of solute per 100 milliliters of solution.
      • Molarity (M): Moles of solute per liter of solution.
      • Molality (m): Moles of solute per kilogram of solvent.
    • Interconversion of Concentration Units: Calculations exist to convert between different units based on solution density and solute molar mass.

    3. Colligative Properties:

    • Colligative properties: Properties of a solution that depend only on the concentration of solute particles, not their identity.
    • Examples:
      • Vapor pressure lowering: Solute presence lowers the solvent's vapor pressure compared to the pure solvent.
      • Boiling point elevation: The boiling point of a solution is higher than that of the pure solvent.
      • Freezing point depression: The freezing point of a solution is lower than that of the pure solvent.
      • Osmotic pressure: The pressure required to prevent the flow of solvent across a semipermeable membrane separating a solution from pure solvent.

    4. Solubility:

    • Solubility: The maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature and pressure.
    • Factors affecting solubility:
      • Nature of solute and solvent: Similar structures tend to be more soluble in each other.
      • Temperature: Generally, solubility increases with temperature.
      • Pressure: For gaseous solutes, solubility increases with pressure.

    5. Ideal and Non-ideal Solutions:

    • Ideal solution: A hypothetical solution that exhibits perfect colligative property behavior based solely on solute concentration.
    • Non-ideal solution: Real-world solutions that deviate from ideal behavior due to interactions between solute and solvent particles. These deviations can be positive or negative.

    6. Applications of Solutions:

    • Solutions are fundamental in various fields, including:
      • Chemistry: Separations, purification, reactions.
      • Biology: Physiological fluids, transport processes.
      • Pharmacy: Drug delivery, formulations.
      • Environmental science: Pollution control, remediation.

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